By Pedro J. Pérez (Ed.),Pedro J. Pérez
Over the prior decade, a lot examine attempt has been dedicated to the layout and synthesis of recent reagents and catalysts which may impact carbon-hydrogen bond activation, often as a result prospect that C−H activation may possibly allow the conversion of inexpensive and ample alkanes into useful functionalized natural compounds.
Alkane C-H Activation through Single-Site steel Catalysis provides the present cutting-edge improvement within the catalytic structures for the catalytic trans-formations of alkanes less than homogeneous stipulations. bankruptcy 1 bargains a entire precis of the most discoveries discovered up to now. bankruptcy 2 experiences the so-called electrophilic activation, initiated through Shulpín within the past due 60s, and the bottom for the Catalytica system. bankruptcy three examines the catalytic borylation of alkanes, found by means of Hartwig, while bankruptcy four offers an up to date imaginative and prescient of the alkane dehydrogenation response. bankruptcy five covers the oxygenation of C-H bonds, a box of large curiosity with bioinorganic im-plications, and eventually bankruptcy 6 provides the functionalization of alkane C-H bonds via carbene or nitrene insertion.
The heritage of C-H bond activation, and the present examine defined during this publication, spotlight the present learn and current the reader with an outlook of this box which is still explored through an more and more visionary and enthusiastic workforce of natural, organometallic, organic and actual chemists.
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